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Doxorubicin Hydrochloride

Pfizer Inc. · FDA-approved approved Small molecule Verified Quality 70/100

Doxorubicin intercalates nucleotide bases and interacts with topoisomerase II to form DNA-cleavable complexes, inhibiting DNA/RNA replication.

Doxorubicin hydrochloride is an anthracycline topoisomerase inhibitor indicated for adjuvant breast cancer treatment and multiple metastatic malignancies. The drug intercalates DNA and forms topoisomerase II-cleavable complexes, with dose-independent pharmacokinetics and metabolism via CYP3A4, CYP2D6, and P-gp. Significant risks include cardiotoxicity (especially with trastuzumab), myelosuppression, and hepatotoxicity, requiring careful patient selection and monitoring. Clinical use requires assessment of cardiac function, hepatic status, and avoidance of contraindicated drug combinations.

At a glance

Generic nameDoxorubicin Hydrochloride
SponsorPfizer Inc.
Drug classAnthracycline topoisomerase inhibitor
TargetDNA topoisomerase II, nucleotide bases
ModalitySmall molecule
Therapeutic areaOncology
PhaseFDA-approved

Mechanism of action

Doxorubicin exerts its cytotoxic effects through multiple mechanisms. The drug intercalates into DNA by inserting itself between nucleotide base pairs, which inhibits the replication of nucleotides and blocks the action of DNA and RNA polymerases. Additionally, doxorubicin interacts with topoisomerase II to form DNA-cleavable complexes, which appears to be a critical mechanism for its cytocidal activity against malignant cells. The toxic effects of doxorubicin on various organs are thought to be related to its nucleotide base intercalation and cell membrane lipid binding activities. Enzymatic reduction at the 7 position and cleavage of the daunosamine sugar yields aglycones accompanied by free radical formation, the local production of which may contribute to the cardiotoxic activity of doxorubicin hydrochloride.

Approved indications

Boxed warnings

Common side effects

Drug interactions

Key clinical trials

Primary sources

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SourceUsed for
ClinicalTrials.govTrial enrolment, design, endpoints, results

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